Используйте шаблонные литералы вместо конкатенации и padStart()
для заполнения начальных нулей.
const now = new Date();
const year = now.getFullYear();
const month = String(now.getMonth() + 1).padStart(2, "0");
const day = String(now.getDate()).padStart(2, "0");
const hour = String(now.getHours()).padStart(2, "0");
const minute = String(now.getMinutes()).padStart(2, "0");
const second = String(now.getSeconds()).padStart(2, "0");
const milli = String(now.getMilliseconds()).padStart(4, "0");
const m_session_startTime = `${year}-${month}-${day} ${hour}:${minute}:${second}:${milli}`;
console.log(m_session_startTime);